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A discussion of the importance of ultraviolet/visible absorption in color vision leads on to the fundamentals of absorption resulting from the shift of an electron from a bonding to an antibonding orbital. The importance of conjugation is stressed, and fluorescence is demonstrated. The program also refers to simple examples of spectra resulting from electron transitions within d-orbitals, and the importance of these spectra in determining the structures of transition metal complexes. (45 minutes)



 
    

Item#: This title is currently not available.
Copyright date: ©1992



Part of the Series : Chemistry Experiments and Processes
     


Only available in the US and Canada.




Interpreting Infrared and N.M.R. Spectra
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An explanation of the theory of infrared absorption is followed by showing a series of spectra demonstrating the major absorption peaks. Shifts within the carbonyl group, and their explanation, are discussed. The N.M.R. portion of the program covers ...(more details)
 
Mass Spectrometry
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An explanation of how a mass spectrometer works is followed by a demonstration of a mass spectrometer in action. The analysis of simple mass spectra is discussed-simple splitting of hydrocarbons, the effect on splitting of heteroatoms in alcohols and...(more details)
 
Transition Metals

A survey of transition metal chemistry begins with a simple introduction to the main properties of transition metal complexes, such as color, magnetism, and complexation, then proceeds to cover the acidity and exchange reactions of transition metal c...(more details)
 
Intermediate H.N.M.R. Spectroscopy

This program takes over where the program Interpreting Infrared and N.M.R. Spectra leaves off, covering shift reagents, deuterium exchange and decoupling, then proceeding to the splitting patterns observed in rigid molecules where the Karplus equatio...(more details)
 
13C N.M.R.
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The importance of the low natural abundance of 13C is stressed in this program, showing how it influences the development of the subject. The program covers types of decoupling, the effect of chemical shift, and the effect of deuterium and 13C labels...(more details)
 


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